For my job as devtest, we get Technet subscriptions, which also works out well for IT guys:
http://technet.microsoft.com/en-us/subscriptions/ms788692.aspxWe don't pay near that price ($349/yr, $249 for 1 year renewals), but it's still a pretty good deal if you're just looking for run-of-the-mill softwware and licenses.
Here's the list of what's available:
Applications (45)
Access 2003
Access 2007
Accounting
Business Contact Manager
Business ScoreCard Manager
Front Page
Groove 2007
Hyper-V Server 2008
Hyper-V Server 2008 R2
InfoPath 2003
InfoPath 2007
Interconnect 2004
Interconnect 2007
Internet Explorer 6.0
Office 2003
Office 2007
Office Communicator 2005
Office Communicator 2007
Office Communicator Web Access
Office Servers 2007
Office XP
OneNote 2003
OneNote 2007
Outlook 2003
Outlook 2007
PerformancePoint Server
Project 2002
Project 2003
Project 2003 Server
Project 2007
Project Portfolio Server 2006
Project Portfolio Server 2007
Publisher 2003
Publisher 2007
SharePoint Designer 2007
Small Business Accounting(App)
Virtual PC 2004
Virtual PC 2007
Virtual PC for Mac 6.1
Virtual PC for Mac 7.0
Virtual Server 2005
Virtual Server 2005 R2
Visio 2002
Visio 2003
Visio 2007
Business Solutions (24)
Dynamics AX 2009
Dynamics AX 4.0
Dynamics Axapta 3.0
Dynamics CRM 1.0
Dynamics CRM 1.2
Dynamics CRM 3.0
Dynamics CRM 4.0
Dynamics GP 10.0
Dynamics GP 7.5
Dynamics GP 8.0
Dynamics GP 9.0
Dynamics NAV 4.0
Dynamics NAV 5.0
Point of Sale 1.0
Small Business Accounting
Small Business Manager Financials 7.5
Small Business Manager Financials 8.0
Small Business Manager Financials 9.0
Small Business Manager FRx (SBM)
Solomon 5.5
Solomon 6.0
Solomon 6.5
Solomon 7.0
Solomon FRx
Operating Systems (26)
Compute Cluster Pack
MS-DOS
Small Business Server 2003
Small Business Server 2003 R2
Windows 3.1 (16-bit)
Windows 3.11 (16-bit)
Windows 3.2 (16-bit)
Windows 7
Windows Advanced Server
Windows CE DirectX Kit
Windows CE Toolkit Visual C++ 6.0
Windows Essential Business Server 2008
Windows Internet Explorer 7
Windows Internet Explorer 8
Windows Server 2003
Windows Server 2003 R2
Windows Server 2008
Windows Server 2008 R2
Windows Services for UNIX 1.0
Windows Services for UNIX 2.0
Windows Services for UNIX 3.0
Windows Services for UNIX 3.5
Windows Small Business Server 2008
Windows Vista
Windows XP
Workgroups 3.11 (16-bit)
Servers (56)
Antigen
Application Virtualization for Terminal Services
BizTalk Server 2002
BizTalk Server 2004
BizTalk Server 2006
BizTalk Server 2006 R2
BizTalk Server Accelerators and Adapters
Commerce Server 2002
Commerce Server 2007
Connected Services Framework
Content Management Server
Customer Care Framework 2005
Customer Care Framework 2008
Customer Care Framework 2009
Desktop Optimization Pack
Exchange Server 2003
Exchange Server 2007
Forefront Client Security
Forefront Client Security Beta
Forefront Security for Exchange Server
Forefront Security for SharePoint
Forefront Server Security Management Console
Forms Server
Groove Server
Host Integration Server 2000
Host Integration Server 2004
Host Integration Server 2006
Identity Integration Server 2003
Identity Lifecycle Manager 2007
ISA Server 2004
ISA Server 2006
Live Communications Server 2003
Live Communications Server 2005
Office Communications Server 2007
Operations Manager 2000
Operations Manager 2005
Project Server
Search Server 2008
SharePoint Server 2001
SharePoint Server 2003
SharePoint Server 2007
SharePoint Server 2007 Search
Speech Server 2004
SQL Server 2000
SQL Server 2005
SQL Server 2008
System Center Capacity Planner
System Center Configuration Manager
System Center Data Protection Manager
System Center Essentials 2007
System Center Mobile Device Manager
System Center Operations Manager
System Center Reporting Manager 2006
System Center Virtual Machine Manager
Systems Management Server 2003
Systems Management Server 2003 R2
TechNet Technical Library (1)
TechNet Technical Library
TechNet Technical Training (4)
Technet Briefings
TechNet Webcasts
Windows Server 2008 Training
Windows Vista Training
Tools and Resources (29)
.NET Compact Framework 1.0
.NET Compact Framework 2.0
.NET Framework 1.0
.NET Framework 1.1
.NET Framework Redistributable 1.0
.NET Framework Redistributable 2.0
.NET Framework Redistributable 3.0
Application Compatibility
Baseline Security Analyzer 2.0.1
Bookshelf Symbol 7
CRC 3.05
Data Analyzer 2002
IIS
ILMerge
Internet Security and Acceleration
Log Parser
MSXML 4.0
Office Resource Kit
Services for Netware
Solver Foundation
SQL Server Migration Assistant
SQL Server Tool (SQLH2)
Translation Glossaries
Windows Hardware Compatibility
Windows Installer
Windows Server Update
Windows Vista Upgrade Advisor 1.0
WinFS
XML Parser 3.0